OK. Sounds good. I would probably ask a lot of questions and do a lot of listening. Some of the things that come to mind are:
How independent is this girl? Does she make friends easily or is her support system of family and friends necessary for her good health -- both physical and mental?
What will the dream job provide? Scratch an itch? Tell her whether or not it's the right one for her? Provide a building block for a future life?
Is money important to her? Is she high maintenance? How will the lack of money affect her? Is she good at money maintenance or will she get into debt easily? Or maybe she doesn't care?
And finally, is she going to a job or running away from something else?